
Instructor: Dr. Barb Dutrow
Room 203, Howe-Russell Building (Old Geology)
Office hours: 2:30-3:30 W or by appointment
Home Page: http://www.geol.lsu.edu/dutrow
E-mail: dutrow@lsu.edu
| Date |
Topic |
Reading,
Assignments To be completed prior to class |
| Aug 25 |
Introduction - Class
overview Minerals as indicators - identification Objectives, Projects |
Review your Mineralogy: Crystallography, Crystal Chemistry, Structures, Coordination |
| Aug 27 |
Review: Basics
of Crystallography, Crystal
Systems, Coordination, Pauling's Rules, Crystal Chemistry, Solid Solution Visualizing Mineral Structures |
K&D: Chapters 3 - 6,
portions as needed |
| Sept 1 |
Knowledge Survey Assignment: Plotting, Stoichiometric calculations |
Compositional Space Plotting on triangular diagrams Calculating mineral formulae |
| Sept 3 |
Analytical Methods in Mineral Chemical Determination and Imaging: Optical, SEM, BSE, CL, EMPA | Geochemical
Instrumentation and Imaging pages from SERC |
| 8 |
Minerals as
geochronometers:
radiogenic dating Introduction to geochronology, Rb/Sr, Sm/Nd, |
Isotope Geology text Homework due |
| 10 |
Geochronometers
con't. - U/Pb (LA-ICP-MS, SIMS-SHRIMP, TIMS) Homework - calculating ages |
RiM v. 53:
Zircon,
ch. 1, 2 Geochemical Instrumentation and Imaging pages from SERC |
| 15 |
Radiogenic: zircon, | RiMG v. 48: Monazite
selected reading ch. 4, 7, 14 RiM v. 5: Titanite |
| 17 |
Radiogeneic:
monazite, titanite |
Geochron homework due |
| 22 |
Radiogenic: garnets Homework - Space Groups |
Garnets: K-D p. 487-490 RiM v. 5, ch. 2 |
| 24 |
Case
Studies of radiogeneic dating Problem set review, optical overview |
|
| 29 |
Minerals as
geochronometers - thermo Ar/Ar: Reliability of ArAr dates Thermochronometers: Feldspars: ksp |
Homework - Space Groups due fsp: K-D p. 446-450, 505-510, |
| Oct. 1 |
Fall Holiday |
|
| 6 |
Thermochronometers: Micas,
Amphiboles, |
amphiboles: K-D p. 446-450,
505-510 RiMG v. 67, ch. 1 micas, K-D p. 456-467, 519-533 |
| 8 |
Minerals as
pressure-temperature indicators Introduction to thermodynamics: Free energy, entropy, enthalpy |
Mineral Stability; P-T, G-X, T-X diagrams |
| 13 |
Introduction to thermodynamics: continued |
Calculating P-T Miscibility Gaps, Exsolution K-D p. 276-281 |
| 15 |
More
thermodynamics KDs |
|
| 20 |
Lab: Project; GSA Annual Meeting | |
| 22 |
Mid-term
Exam |
|
| 27 |
More
thermodynamics Effect of solid solution on mineral stabilities: PT determinations, GASP, garnet biotite |
D. Waters: Mineral thermobarometry |
| 29 |
Effect of solid solution on mineral stabilities: Activity models: ideal, non-ideal, fugacity |
D.
Waters: Energy of mixing D. Waters: Ideal mixing , non-ideal |
| Nov. 3 |
P-T
indicators - Single mineral thermobarometers: Saturation surfaces Ti-in-biotite; Ti-in-zircon, Zr-in-rutile |
Rutile Ti in Biotite Watson et al. (2006) |
| 5 |
Single mineral thermobarometers: Ti-in-biotite; Ti-in-zircon, Zr-in-rutile |
Zircon: RiMG v. 53, ch. 4 Biotite: Henry et al. link for program Henry et al. (2005) Am.Min. 90:316-328 Rutile: Spear et al. (2006) |
| 10 |
P-T indicators - Plagioclase-Amphibole, Pyroxenes: Cpx-Opx | Pyroxenes:
K-D p. 446-450,
505-510 RiM v. 7, ch 2 |
| 12 |
Multiequilibria approach | |
| 17 |
Minerals as provenance indicators | Armstrong et al. (2009) |
| 19 |
Provenance: Tourmaline, Amphiboles, pyroxene, garnets | Henry and Dutrow (1992) (1996) Hawthorne and Henry (1999) |
| 24 |
Provenance:
Oxides, zircon, rutile |
|
| 26 |
Thanksgiving Holiday
|
|
| Dec 1 |
Project presentations |
|
| 3 |
Project presentations |
|
| Fri, Dec 11 5:30-7:30pm |
Final
Exam |