Geol. 4043: Earth
Materials
and the Environment
Spring 2023
Tuesday - 3:00 - 5:50 pm
E207 Howe-Russell Building (E = East)
"Everything is a poison, nothing is a poison, the
dose alone makes the poison."
- Paracelsus, 1493-1541
Instructor: Dr. Barb Dutrow, Professor
Room 203 Howe-Russell Building (Old
Geology = West)
Office hours: By appointment M-F
E-mail: dutrow@lsu.edu
Note: e-mail is answered within 24 hrs; from 9am - 6 pm M - F
TA: Xiao Tan
Room E340a Howe-Russel
Building
Office Hours: 10:30 - noon T,
Th and by appointment
Required Text: Reading materials for
the course are assembled into a packet from the Mineralogical
Society of America.
Refer
to Dr. Dutrow's email for specific instructions.
Reading assignments should
be completed prior to class.
Recommended Text: Klein
& Dutrow, 2007, Manual of Mineral Science, 23rd
Edition
Evaluation: Knowledge of materials, Critical thinking
and analysis of material is an integral portion of this
class.
In class participation, preparation for discussion
materials, assignments, and
presentations contribute to the overall
grading.
Class evaluation is based on two tests (20% midterm and 20%
final exam), two projects (10% energy forum, 20%
analytical project),
20% assigned class presentations (oral and
written) including environmental reports from the
media, 10% class participation/quizzes.
Grading follows university rules for +/- for each letter
grade: A+ = 97-100 A = 94-96 A- = 93-90.
Note: Texting and use of cellular devices is not permitted during
class unless explicitly authorized by Prof. Dutrow
Class
absences should be reported PRIOR to class.
Course Learning OBJECTIVES:
This course is designed to enhance critical thinking and content
knowledge including:
ACKNOWLEDGEMENT OF FUNDING
The use of the analytical
instruments within the Department of Geology & Geophysics
(Optical CL Microscope; Bruker S2 PUMA XRF; Keyence VHX-7100
Automated Digital Microscope) and the Shared Instrumentation
Facility (JEOL JXA-8230 EPMA) is supported by a generous gift
from Chevron.
Tentative Lecture and Exam Schedule
check www.geol.lsu.edu/dutrow/env for
updates
Date | topic |
Assignments and Reading
prior to class
Come with answers prepared to questions. MMS = Manual of Mineral Sciences, Klein & Dutrow; RiM
= Reviews in Mineralogy; IEA report 2021- 2022 - useful resource |
January
Date | Topic |
Assignments, Reading Prior to
Class |
17 | Introduction Class overview: expectations, course-embedded assignments, presentations, critical thinking projects LSU library informational resources Earth Materials review, mineralogy, petrology, fluids Fossil fuel energy, the carbon cycle, and global warming
|
Review Mineralogy - Paulings Rules (solid solution,
coordination number, mineral structures, chemistry); KD
chpt 4. Fluids - geochemistry resource: Elements 2020 p. 375-380.
Hydrothermal fluids |
20 (Friday) |
G&G Seminar: Lessons learned from
global CO2 storage projects |
3:30 pm, E130 HRK |
24 |
The landscape of reporting Energy and
Environmental Science Sustainability - what it is? How large is the ecosystem? ESG Solutions to mitigate CO2
- carbon emissions |
Reading: Wildavsky, A. in But is it
True? Come prepared for discussion on how to read an environmental article, bring an article Elements, 2007, v. 3 Macfarlane, A."Energy: The Issue of the 21st Century" p. 165-170 Schrag, D."Confronting the Climate - Energy Challenge". p. 171-178 |
31 |
Solutions to mitigate CO2 - carbon emissions Geologic carbon sequestration - options - mineral trapping, solution trapping, - CO2 phase diagram - then and now Mineral Surfaces; Reactivity, porosity, permeability, Overview of Energy Forum assignment, class presentations |
Elements,
2007, v.3 Friedman, S.J., "Geologic Carbon Dioxide Sequestration" p. 179-184 Elements, 2008, v. 4 -Perspectives: v. 4 p 293-299 -Oeklers, E and Cole, D., Carbon Dioxide Sequestration: A solution to a global problem. p 305-310. -Rubin, E. CO2 Capture and transport. p.311-318 -Ocean storage - 319-324 -Benson, S. and Cole, D., CO2 sequestration in deep sedimentary basins. p. 325-332. -Oelkers et al. Mineral carbonation of CO2. p333-337. Previous studies: NAS workshop reports: Carbon management; CO2 dilemma |
February
3 (Friday) 4pm |
Required Attendance: LSU G&G Centennial Energy Forum |
Report due Feb. 14 (Assignment on Moodle) |
7 |
Guest
Lecturer - Dr. Matt Loocke Overview of analytical methods in the Geosciences for solid materials Tour: The Chevron Geomaterials Lab; facilities for imaging and chemistry of Earth Materials; Optical CL, microscopy, electron microprobe analyses |
Reading to be assigned - SERC website - geochemical instrumentation overviews https://serc.carleton.edu/research_education/geochemsheets/browse.html#ebeam EMPA, XRF |
14 |
Discussion/ Debate: Energy
Forum Geologic Carbon Sequestration (cont), - serpentinites, rocks, - natural analogs (class presentations) Discussion/Debate: Pros, cons of carbon sequestration, LA options Risk Assessment: What is it? What are the uncertainties associated with Risk Management |
Elements, 2008,
Perspectives: v. 4 p 293-299 Elements, 2013, v. 9 no 2
RiMG 77 Geologic Carbon
Sequestration |
21 |
Think Green (and Gold and Purple) |
Mardi Gras Holiday |
28 |
Low Carbon Energy Sources -
Renewable Energy and the Energy Transition: How green is
green? Wind
and Solar Energy - materials needed
|
Elements
8; 2012, REEs -Chakhmouradian & Naldrett, REEs in
Ig rocks, p.
347 – 354 -Kumicky et al., REEs in China, 361-368 - Mariano, REE in US
Review REE minerals,
mineralogy, |
March
7 |
Geologic settings of REEs;
Pegmatites, carbonatites, mineralogy and petrology Specific sources: Mountain Pass, CA ores, bastnasite, China, etc. Global markets, refining and the environment Mining in the US vs elsewhere: costs and consequences Lab: REE bearing minerals |
Elements 8, 2012, REEs -Chakhmouradian & Naldrett, REEs in Ig rocks, p. 347 – 354 -Kumicky et al., REEs in China, 361-368 Elements, 2021, v 17, no
5, Carbonatites -Kamenetsky et al.,, Carbonatites, p.
302-314 -Anenburg et al., Formation of RE
Deposits, p. 327-332 -Christy et al, Mineralogy of
carbonatites, p. 333-338 Reading from the literature Aspects of Mining: Toxic Metals and surfaces, the US 1862 mining law |
14 |
Spring Break |
think Minerals |
21 |
Project discussion: Overview of course-embedded analytical project sample assignment CL imaging, review of EMPA Sign up for lab time Lab: Optical microscopy on your sample CL demonstration, thin section scanning |
Mineralogy of REE deposits |
Chemical analyses of your sample with EMP, assigned time |
prepare by knowing likely minerals in your
sample |
|
28 |
Going Electric vehicles: Critical Materials
needed for low carbon - batteries, Lithium Li minerals, sources, issues Lab: Analytical project - Determining mineral stoichiometry, mineralogy |
IEA report 2021- 2022 Elements, 2020, v. 15, no 4, Lithium Bibenne, et al., Society’s dependence
on Li, p. 265- 270 Grew, Li minerals, p. 235-240 Bowell, et al., Li Resources, p. 259-264
Elements, 2013, v. 9 no 2 Butt, et al., nicket Laterite Ore Deposits, p. 123-127 |
last two weeks |
Analytical project - obtaining chemistry of
rocks with REE-bearing minerals, focus on carbonatites ACKNOWLEDGEMENT OF
FUNDING |
Schedule ~ 2 hrs time in EMP lab with Dutrow/Loocke |
4 |
Geothermal Energy: Introduction,
Overview and Energy Prospects for future, pros, cons |
Readings from the literature |
11 |
Geothermal
Energy: Case studies, EGS in Louisiana; pros, cons Guest Lecturer - either 4 or 11 April |
|
14 (Friday) |
MSA Distinguished Lecturer - Dr. Jay Thomas,
Syracuse Univ. Pressure determinations in rocks |
Please attend |
18 |
Nuclear
Energy - Fuel Cycles, Pros, Cons Nuclear Waste: HL, LL,
TRU; Front End Nuclear Waste: Back End - Storage/Disposal/Management options/ Geologic Repositories; US solution - Geologic Repository at Yucca Mtn., NV; History and Plan B Materials for encasement: storage/adsorption: Three-mile island - the nuclear stigma; Lab: materials for containment, betafite, pyrochlor, garnets |
Elements, 2006, v. 2 Nuclear Energy - Elements Magazine, 2006, v. 2 Ewing "The nuclear fuel cycle: A role for mineralogy and geochemistry" Abdelouas, A. "Uranium Mill Tailings:" p. 335-341. Bruno, J.
and Ewing, R., "Spent
Nuclear Fuel". p. 343-349.
Nuclear Waste Legislation - Mar.2000 |
21 (Friday) |
REQUIRED Attendance: Centennial Lecture - Prof. Rodney Ewing, Nuclear Energy |
Stanford Univ, NAS member |
25 |
Nuclear Accident - Fukushima new reactors giving presentations, peer evaluations of presentations, rubric for such. Poster preparation |
Elements 2011, v. 8 Fukushima p. 181-221 |
28 - Friday |
LSU G&G Rock Star Poster Competition |
Present poster on your analytical project! |
May
2 |
STUDENT Oral PRESENTATIONS of research project | |
11 (Th) 7:30 - 9:30 AM |
FINAL
EXAM |
COMPREHENSIVE |
Other links: Learn more about the periodic table, minerals and gems
Other useful reading materials:
But is
it True? A Citizens Guide to Environmental Issues,
A. Widavsky, 1995. Harvard Univ. Press
Others for reference or an
interesting read.
Silent
Spring, Rachael Carson, 1962, Houghton Mifflin Co.
Boston
(A classic, widely credited with
starting the environmental movement; bringing to light the
consequences of chemicals in the environment- ecology).
Environmental Mineralogy,
2000, Eds. David J. Vaughn and Roy A. Wogelius.
EMU Notes in Mineralogy
2. Eotvos University Press, Budapest.
An
Inconvenient Truth. 2006. Al Gore. Rodale
Press.
Class Policies:
Attendance: Mandatory. If you are going to be absent, you
must notify Prof. Dutrow ahead of time for an excused
absence.
Make up
exams: Lecture exams will be 5 essay questions
Makeup
quizzes: None will be given.
Cell
Phones: No cell phone use is permitted during class. If you
use your cell phone, you will be asked to leave class.
Class is a concentrated study time, if you are on your phone, you
are distracted.
Students
with disabilities: Louisiana
State
University is committed to providing reasonable
accommodations for all persons with
disabilities.
The syllabus is available in alternate formats
upon request. If you are seeking classroom
accommodations under the Americans with
Disabilities Act,
you are required to register with the Disability
Services (DS). DS is located in 115 Johnston
Hall. Phone is 225/ 578-5919.
To receive academic accommodations for this
class, please obtain the proper DS forms and
meet with me at the beginning of the semester.
Code of
Student Conduct: Louisiana
State University is an interactive community in which
students, faculty, and staff together strive to pursue
truth, advance learning, and
uphold the highest standards of performance in an academic
and social environment. It is a community that fosters
individual development and the creation of bonds that
transcend the time spent within its gates. To demonstrate
my pride in LSU, as a member of its community, I will:
The
continued success of LSU depends on the faithful commitment
by each community member to these, our basic principles.
There are
two areas that we will be particularly alert for in this
class:
(1)
Plagiarism is an
extremely serious violation of academic integrity. The Code
of Student Conduct defines plagiarism as “the unacknowledged
inclusion,
in work submitted for credit, of someone else’s words,
ideas, or data.” (8.1-C.6)
(2)
Copying - Copying
from another student's test paper or assignment.
Alcohol Policy (PS-67 Illegal Use of Drugs
and Alcohol Misuse): Louisiana State University is committed to
maintaining an environment which supports the research,
teaching, and service mission
of the University. Although the University respects an
employee's right to privacy, the illegal use of drugs or
alcohol within the University community interferes with
the accomplishment of the
University's mission.
Louisiana State Law prohibits the consumption,
possession, distribution, possession with intent to
distribute, or manufacture of drugs described as
controlled dangerous
substances in the Louisiana Revised Statutes 40:964; and
other statutes define the illegal possession and/or use
of alcohol. As
such, the Department has reaffirmed the University
policy of
alcohol-free and drug-free environment on University
property at all times and in areas and at times and
locations where an assembly of students and faculty
would be viewed as representative of LSU
(field trips and field camp property as both
represent LSU)
updated 01/18/2023
(c) Barbara L. Dutrow